Evaluation of Alternative Additives to SeO2 in the Electrodeposition of Metallic Manganese
DOI:
https://doi.org/10.36790/epistemus.v15i31.198Keywords:
electrodeposition, manganese, additivesAbstract
The demand for metallic products obtained from the mining and metallurgical industry has increased over time due to the wide range of uses they have, an example of which is manganese. In Mexico, ores containing this element are used as raw material in the iron and steel industry, without taking advantage of its value as a marketable product. One example is metallic manganese, which is obtained by the electrodeposition process. However, this process has the disadvantage of using SeO2 as an additive to inhibit the generation of hydrogen evolution by the water reduction. This element is highly toxic and environmentally polluting, so this work focuses on finding alternative additives that are more environmentally friendly without significantly affecting current efficiency and energy consumption parameters.
Downloads
References
C. M. D. MEXICO, Informe anual 2020. Mèxico, 2020, p. 339.
F. Habashi, V. VerlagsgesellschaftmbH., Ed. Handbook of extractive metallurgy. 1997, p. 2426.
M. Gonsalves and D. Pletcher, "A study of the electrodeposition of manganese from aqueous chloride electrolytes," Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, vol. 285, no. 1, pp. 185-193, 1990/06/11/ 1990. https://doi.org/10.1016/0022-0728(90)87120-9 DOI: https://doi.org/10.1016/0022-0728(90)87120-9
L. C. Tan, Y. V. Nancharaiah, E. D. van Hullebusch, and P. N. L. Lens, "Selenium: environmental significance, pollution, and biological treatment technologies," Biotechnology Advances, vol. 34, no. 5, pp. 886-907, 2016/09/01/ 2016. https://doi.org/10.1016/j.biotechadv.2016.05.005 DOI: https://doi.org/10.1016/j.biotechadv.2016.05.005
Q. Wei, X. Ren, J. Du, S. Wei, and S. Hu, "Study of the electrodeposition conditions of metallic manganese in an electrolytic membrane reactor," Minerals Engineering, vol. 23, no. 7, pp. 578-586, 2010/06/01/ 2010. https://doi.org/10.1016/j.mineng.2010.01.009 DOI: https://doi.org/10.1016/j.mineng.2010.01.009
J. Gong and G. Zangari, "Electrodeposition of sacrificial tin–manganese alloy coatings," Materials Science and Engineering: A, vol. 344, no. 1, pp. 268-278, 2003/03/15/ 2003. https://doi.org/10.1016/S0921-5093(02)00412-4 DOI: https://doi.org/10.1016/S0921-5093(02)00412-4
Griskonis, E., Sulcius, and Zmuidzinaviciene, "Influence of temperature on the properties of Mn coatings electrodeposited from the electrolyte containing Te(VI) additive," Journal of Applied Electrochemistry, vol. 44(10), p. 1125, 2014. 10.1007/s10800-014-0733-8 DOI: https://doi.org/10.1007/s10800-014-0733-8
J. Rojas-Montes, R. Pérez-Garibay, and A. Uribe-Salas, "The Effects of an Anionic Membrane on the Electrodeposition of Manganese Ions: A Kinetic and Statistical Study. Journal of the Electrochemical Society, 161: D67-D72.," 2013. 10.1149/2.048401jes DOI: https://doi.org/10.1149/2.048401jes
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2022 EPISTEMUS
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
The magazine acquires the patrimonial rights of the articles only for diffusion without any purpose of profit, without diminishing the own rights of authorship.
The authors are the legitimate owners of the intellectual property rights of their respective articles, and in such quality, by sending their texts they express their desire to collaborate with the Epistemus Magazine, published biannually by the University of Sonora.
Therefore, freely, voluntarily and free of charge, once accepted the article for publication, they give their rights to the University of Sonora for the University of Sonora to edit, publish, distribute and make available through intranets, Internet or CD said work, without any limitation of form or time, as long as it is non-profit and with the express obligation to respect and mention the credit that corresponds to the authors in any use that is made of it.
It is understood that this authorization is not an assignment or transmission of any of your economic rights in favor of the said institution. The University of Sonora guarantees the right to reproduce the contribution by any means in which you are the author, subject to the credit being granted corresponding to the original publication of the contribution in Epistemus.
Unless otherwise indicated, all the contents of the electronic edition are distributed under a license for use and Creative Commons — Attribution-NonCommercial-ShareAlike 4.0 International — (CC BY-NC-SA 4.0) You can consult here the informative version and the legal text of the license. This circumstance must be expressly stated in this way when necessary.
The names and email addresses entered in this journal will be used exclusively for the purposes established in it and will not be provided to third parties or for their use for other purposes.
