Strategies for the removal of calcium and magnesium from waters in the flotation process of complex sulfides.
DOI:
https://doi.org/10.36790/epistemus.v18i37.377Keywords:
Mining, Mineral flotation, Water treatmentAbstract
Mining is closely related to the use of water, as it is essential for the operation of its processes. In response to the need to preserve this resource, practices have been developed to reduce the consumption of fresh water in the flotation processes. However, the increased use of recycled water in flotation sometimes has negative effects on both the recovery of valuable minerals and grade of the obtained concentrate. The adverse effects observed result into decreased selectivity and yield due to the presence of Ca2+ and Mg2+ ions in the recycled waters. This article reviews some treatment techniques that may be applicable to recycling water in the flotation of sulfide minerals.
Downloads
References
G. Levay, R. S. C. Smart y W. M. Skinner, "The impact of water quality on flotation performance," The journal of The South African Institute of Mining and Metallurgy, vol. marzo/abril, pp. 69-75, 2001.
S. D. Ojeda-Villegas y A. Uribe-Salas, "Remoción de los iones Ca2+ y Mg2+ de las aguas de flotación de sulfuros complejos mediante la adición de carbonato de sodio," Epistemus, vol. 17, pp. 124-1831, 2023, DOI: https://doi.org/10.36790/epistemus.v17i34.255. DOI: https://doi.org/10.36790/epistemus.v17i34.255
C. Moraga, W. Kracht y J. M. Ortiz, "Water consumption assessment in mineral processing integrating weather information and geometallurgical modeling," Minerals Engineering, vol. 201, 108162, 2023/10/01/ 2023, DOI: https://doi.org/10.1016/j.mineng.2023.108162 DOI: https://doi.org/10.1016/j.mineng.2023.108162
S. D. Ojeda Villegas, A. Uribe-Salas, G. Pérez, Roberto y M. Elizondo-Álvarez, "A kinetic and thermodynamic study of the removal of calcium and magnesium from aqueous solutions similar to those of complex sulphide flotation by the addition of sodium carbonate," Canadian Metallurgical Quarterly, 2023, DOI: https://doi.org/10.1080/00084433.2023.2285587. DOI: https://doi.org/10.1080/00084433.2023.2285587
L. M. Shengo, S. Gaydardzhiev y N. M. Kalenga, "Malachite and heterogenite behavior during the locked-cycled recycling of process water in flotation of copper-cobalt oxide ores," International Journal of Mineral Processing, vol. 157, pp. 152-162, 2016, DOI: http://dx.doi.org/10.1016/j.minpro.2016.10.009. DOI: https://doi.org/10.1016/j.minpro.2016.10.009
Secretaría de Medio Ambiente y Recursos Naturales. (2021). Buenas prácticas para el uso del agua en la industria minera de México. DOI: https://doi.org/10.24850/b-imta-2021-02 DOI: https://doi.org/10.24850/b-imta-2021-02
E. R. Bazúa-Rueda et al., "Mining, Water and Society: Recycling of Mining Effluents as a Social Solution to the Use of Water in Mexico," in Water Availability and Management in Mexico, E. M. Otazo-Sánchez, A. E. Navarro-Frómeta y V. P. Singh Eds. Cham: Springer International Publishing, 2020, pp. 389-411. DOI: 10.1007/978-3-030-24962-5_19. DOI: https://doi.org/10.1007/978-3-030-24962-5_19
G. I. Dávila-Pulido y A. Uribe-Salas, "Effect of calcium, sulphate and gypsum on copper-activated and non-activated sphalerite surface properties," Minerals Engineering, vol. 55, pp. 147-153, 6 octubre 2013-2014. DOI: https://doi.org/10.1016/j.mineng.2013.10.006
M. Sinche-Gonzalez y D. Fornasiero, "Understanding the effect sulphate in mining-process water on sulphide flotation," Minerals Engineering, vol. 165, pp. 1-10, 2021, DOI: https://doi.org/10.1016/j.mineng.2021.106865. DOI: https://doi.org/10.1016/j.mineng.2021.106865
G. Bulut y Ü. Yenial, "Effects of major ions in recycled water on sulfide minerals flotation," Minerals & Metallurgical Processing, vol. 33, pp. 137-143, 2016, DOI: https://doi.org/10.19150/mmp.6750. DOI: https://doi.org/10.19150/mmp.6750
S. R. Grano, P. L. M. Wong, W. Skinner, N. W. Johnson y J. Ralston, "Detection and control of calcium sulphate precipitation in the lead circuit of the Hilton concentrator of Mount Isa Mines Limited, Australia," Proc. XIX International Mineral Processing Congress, vol. 10, pp. 1139-1163, 1995. DOI: https://doi.org/10.1016/S0892-6875(97)00100-3
G. I. Dávila-Pulido, A. A. González-Ibarra, M. Garza-García y D. A. Charles, "Effect of Magnesium on the Hydrophobicity of Sphalerite," Minerals, vol. 11, no. 12, DOI: 10.3390/min11121359. DOI: https://doi.org/10.3390/min11121359
E. Bustos-Flores, M. Elizondo-Álvarez y A. Uribe-Salas, "Thermodynamic and experimental studies on the removal of calcium and sulfate ions from recycling waters of complex-sulfide flotation operations.," Tansactions of Nonferrous Metals Society of China, vol. 31, pp. 3116-3127, 2021, DOI: https://doi.org/10.1016/S1003-6326(21)65720-5. DOI: https://doi.org/10.1016/S1003-6326(21)65720-5
M. Ejtemaei, C. Plackowski y A. V. Nguyen, "The effect of calcium, magnesium and sulphate ions on the surface properties of copper activated sphalerite," Minerals Engineering, vol. 89, pp. 45-51, enero 2016. DOI: https://doi.org/10.1016/j.mineng.2016.01.005
A. D. Guerrero-Flores, A. Uribe-Salas, G. I. Dávila-Pulido y J. M. Flores-Álvarez, "Simultaneous removel of calcium and sulfate ions from flotation water of complex sulfides " Minerals Engineering, vol. 123, pp. 28-34, 2018. DOI: https://doi.org/10.1016/j.mineng.2018.04.024
S. R. Rao y J. A. Finch, "A review of water re-use in flotation," Minerals Engineering, vol. 2, pp. 65-85, 1989. DOI: https://doi.org/10.1016/0892-6875(89)90066-6
J. H. Salgado, "Agua y minería (parte II)," Perspectivas IMTA, vol. 8, 2021, DOI: https://doi.org/10.24850/b-imta-perspectivas-2021-07 DOI: https://doi.org/10.24850/b-imta-perspectivas-2021-07
L. A. Pacheco Pérez y M. d. C. Durán Domínguez de Bazúa, "Uso del agua en la industria minera. Parte 2: Estudio de opciones para reciclar el agua del proceso," Tecnología, Ciencia, Educación vol. 22, pp. 15-29, 2007
A. Abidi, K. Boujounoui, E. Amari, A. Bacaoi y A. Yaacoubi, "Contribution to Improve Water Process Recycling in the Flotation Plant of a Complex Zn-Pb-Cu Sulphide Ore," Journal of Mining Science, vol. 55, pp. 658-667, 2019, DOI: https://doi.org/10.1134/S1062739119046014. DOI: https://doi.org/10.1134/S1062739119046014
A. Di Feo, C. M. Hill-Svehla, B. R. Hart, K. Volchek, L. Morin y A. Demers, "The effects of water recycling on flotation at a North American concentrator," Minerals Engineering, vol. 170, pp. 1-25, 2021, DOI: https://doi.org/10.1016/j.mineng.2021.107037. DOI: https://doi.org/10.1016/j.mineng.2021.107037
I. Muzinda y N. Schreithofer, "Water quality effects on flotation: Impacts and control of residual xanthates," Minerals Engineering, vol. 125, 2018, DOI: https://doi.org/10.1016/j.mineng.2018.03.032. DOI: https://doi.org/10.1016/j.mineng.2018.03.032
M. Elizondo-Álvarez, "Colectores alternativos al xantato: Estudio de la adsorción de hidroxamatos sobre galena (PbS), cerusita (PbCO3) y anglesita (PbSO4) y evaluación de su respuesta a la flotación," Doctorado, Ingeniería Metalúrgica y Cerámica, CINVESTAV-IPN, México, 2021.
J. Chen, "The interaction of flotation reagents with metal ions in mineral surfaces: A perspective from coordination chemistry," Minerals Engineering, vol. 171, p. 107067, 2021/09/01/ 2021, DOI: https://doi.org/10.1016/j.mineng.2021.107067. DOI: https://doi.org/10.1016/j.mineng.2021.107067
B. A. Wills, "Tratamiento de menas y recuperación de minerales," in Tecnología de procesamiento de minerales, A. H. Cerdán y A. T. Reyes Eds., 2 ed. México: Limusa, S.a. de C.V., 1994, cap. 12, pp. 345-420.
A. M. Nowosielska, A. N. Nikoloski y D. F. Parsons, "The effects of saline water on the recovery of lead y zinc sulfide during froth flotation," Minerals Engineering, vol. 202, p. 108236, 2023/11/01/ 2023, DOI: https://doi.org/10.1016/j.mineng.2023.108236. DOI: https://doi.org/10.1016/j.mineng.2023.108236
E. El-ammouri, M. Mirnezami, D. Lascelles y J. A. Finch, "Aggregation index and methodology to study the role of magnesium in aggregation of sulphide slurries," CIM Bulletin vol. 95, pp. 67-72, 2002.
M. Zanin, H. Lambert y C. A. d. Plessis, "Lime use and functionality in sulphide mineral flotation: A review," Minerals Engineering, vol. 143, pp. 1-14, 2019, DOI: https://doi.org/10.1016/j.mineng.2019.105922. DOI: https://doi.org/10.1016/j.mineng.2019.105922
S. Motaung, J. Maree, M. D. Beer, L. Bologo, D. Theron y J. Baloyi, "Recovery of Drinking Water and By-products from Gold Mine Effluents," International Journal of Water Resources Development, vol. 24, pp. 433-450, 2008, DOI: https://doi.org/10.1080/07900620802150475. DOI: https://doi.org/10.1080/07900620802150475
S. G. Benner, D. W. Blowes y C. J. Ptacek, "A full-scale porous reactive wall for prevention of acid mine drainage," Groundwater Monitoring & Remediation, pp. 99-107, 1997. DOI: https://doi.org/10.1111/j.1745-6592.1997.tb01269.x
F. Ikumapayi, B. Johansson y H. R. Kota, "Recycling of process water : effect of calcium and sulphate ions on flotation of galena," Minerals Engineering, vol. 39, pp. 77-88, 2012, DOI: https://doi.org/10.1016/j.mineng.2012.07.016. DOI: https://doi.org/10.1016/j.mineng.2012.07.016
L. L. October, K. C. Corin, M.S. Manono, N. Schreithofer y J. G. Wiese, "A fundamental study considering specific ion effects on the attachment of sulfide minerals to air bubbles," Minerals Engineering, vol. 151, 2020, DOI: https://doi.org/10.1016/j.mineng.2020.106313. DOI: https://doi.org/10.1016/j.mineng.2020.106313
D. Lascelles, J. A. Finch y C. SUI, "Depressant action of Ca and Mg on flotation of Cu activated sphalerite," Canadian Metallurgical Quarterly vol. 42, pp. 133-140, 2002. DOI: https://doi.org/10.1179/000844303794535951
H. Jin, Y. Yu y X. Chen, "Electrochemical precipitation for water and wastewater treatment," Process Safety and Environmental Protection, vol. 184, pp. 1011-1016, 2024/04/01/ 2024, DOI: https://doi.org/10.1016/j.psep.2024.02.044. DOI: https://doi.org/10.1016/j.psep.2024.02.044
R. I. Jeldres, E. C. Pieceros, J. A. Valenzuela y P. A. Robles, "Remoción de calcio y magnesio en agua de mar para mejorar la concentración de sólidos en la descarga de espesadores " Información tecnológica vol. 30, pp. 291-298, 2019. DOI: https://doi.org/10.4067/S0718-07642019000500291
S. Farmanbordar, D. Kahforoushan y E. Fatehifar, "A new method in the removal of Ca and Mg ions from industrial wastewater," Desalination and Water Treatment, vol. 57/60, pp. 37-41, 2015, DOI: https://doi.org/10.1080/19443994.2015.1024744. DOI: https://doi.org/10.1080/19443994.2015.1024744
R. I. Jeldres, M. P. Arancibia-Bravo, A. Reyes, C. E. Aguirre, L. Cortes y L. A. Cisternas, "The impact of seawater with calcium and magnesium removel for the flotation of copper-molybdenum sulphide ores," Minerals Engineering, vol. 109, pp. 10-13, 2017. DOI: https://doi.org/10.1016/j.mineng.2017.02.003
C. Pujiastuti, Y. Ngatilah, K. Sumada y S. Muljani, "The effectiveness of sodium hydroxide (NaOH) and sodium carbonate (Na2CO3) on the impurities removal of saturated salt solution," The 2nd International Joint Conference on Science and Technology, vol. 953, pp. 1-5, 2018. DOI: https://doi.org/10.1088/1742-6596/953/1/012215
C. Pujiastuti, K. Sumada, Y. Ngatilah y P. Hadi, "Removal of Mg2+, K+, SO4 -2 ions from seawater by precipitation method," MATEC Web of Conferences, vol. 58, pp. 1-4, 2016. DOI: https://doi.org/10.1051/matecconf/20165801022
K. Zeppenfeld, "Electrochemical removal of calcium and magnesium ions from aqueous solutions," Desalination vol. 277, pp. 99-105, 2011. DOI: https://doi.org/10.1016/j.desal.2011.04.005
A. Uribe-Salas y R. Espinosa-Gómez, "Tratamiento del agua de alimentación a molinos de la Planta 2 Unidad Sabinas ", ed, 2010.
R. Espinosa-Gómez, A. Uribe-Salas, J. Lira y A. Guerra, "Integral metallurgy-the case of peñoles mines and concentrators," presentado en Proc. XXVIII International Minning Convention, AIMMGM, Veracruz, México, 2009.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2024 EPISTEMUS
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.
The magazine acquires the patrimonial rights of the articles only for diffusion without any purpose of profit, without diminishing the own rights of authorship.
The authors are the legitimate owners of the intellectual property rights of their respective articles, and in such quality, by sending their texts they express their desire to collaborate with the Epistemus Magazine, published biannually by the University of Sonora.
Therefore, freely, voluntarily and free of charge, once accepted the article for publication, they give their rights to the University of Sonora for the University of Sonora to edit, publish, distribute and make available through intranets, Internet or CD said work, without any limitation of form or time, as long as it is non-profit and with the express obligation to respect and mention the credit that corresponds to the authors in any use that is made of it.
It is understood that this authorization is not an assignment or transmission of any of your economic rights in favor of the said institution. The University of Sonora guarantees the right to reproduce the contribution by any means in which you are the author, subject to the credit being granted corresponding to the original publication of the contribution in Epistemus.
Unless otherwise indicated, all the contents of the electronic edition are distributed under a license for use and Creative Commons — Attribution-NonCommercial-ShareAlike 4.0 International — (CC BY-NC-SA 4.0) You can consult here the informative version and the legal text of the license. This circumstance must be expressly stated in this way when necessary.
The names and email addresses entered in this journal will be used exclusively for the purposes established in it and will not be provided to third parties or for their use for other purposes.