Evaluation of Alternative Additives to SeO2 in the Electrodeposition of Metallic Manganese

Authors

  • Cesar Guillermo Flores Santillán Tecnológico Nacional de México/IT Durango, Maestría en Sistemas Ambientales
  • Jaime Cristóbal Rojas Montes Tecnológico Nacional de México/ IT Durango https://orcid.org/0000-0003-4344-9046
  • Víctor Jesús Martínez Gómez Tecnológico Nacional de México/ IT Durango https://orcid.org/0000-0002-5313-3494
  • Diana Cristina Martínez Casillas Tecnológico Nacional de México/ IT Durango https://orcid.org/0000-0002-0128-3335
  • Rafael Lucho Chigo Tecnológico Nacional de México/ IT Durango https://orcid.org/0000-0003-4151-6911
  • Félix Alonso Alcázar Medina Tecnológico Nacional de México/ IT Durango

DOI:

https://doi.org/10.36790/epistemus.v15i31.198

Keywords:

electrodeposition, manganese, additives

Abstract

The demand for metallic products obtained from the mining and metallurgical industry has increased over time due to the wide range of uses they have, an example of which is manganese. In Mexico, ores containing this element are used as raw material in the iron and steel industry, without taking advantage of its value as a marketable product. One example is metallic manganese, which is obtained by the electrodeposition process. However, this process has the disadvantage of using SeO2 as an additive to inhibit the generation of hydrogen evolution by the water reduction. This element is highly toxic and environmentally polluting, so this work focuses on finding alternative additives that are more environmentally friendly without significantly affecting current efficiency and energy consumption parameters.

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References

C. M. D. MEXICO, Informe anual 2020. Mèxico, 2020, p. 339.

F. Habashi, V. VerlagsgesellschaftmbH., Ed. Handbook of extractive metallurgy. 1997, p. 2426.

M. Gonsalves and D. Pletcher, "A study of the electrodeposition of manganese from aqueous chloride electrolytes," Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, vol. 285, no. 1, pp. 185-193, 1990/06/11/ 1990. https://doi.org/10.1016/0022-0728(90)87120-9 DOI: https://doi.org/10.1016/0022-0728(90)87120-9

L. C. Tan, Y. V. Nancharaiah, E. D. van Hullebusch, and P. N. L. Lens, "Selenium: environmental significance, pollution, and biological treatment technologies," Biotechnology Advances, vol. 34, no. 5, pp. 886-907, 2016/09/01/ 2016. https://doi.org/10.1016/j.biotechadv.2016.05.005 DOI: https://doi.org/10.1016/j.biotechadv.2016.05.005

Q. Wei, X. Ren, J. Du, S. Wei, and S. Hu, "Study of the electrodeposition conditions of metallic manganese in an electrolytic membrane reactor," Minerals Engineering, vol. 23, no. 7, pp. 578-586, 2010/06/01/ 2010. https://doi.org/10.1016/j.mineng.2010.01.009 DOI: https://doi.org/10.1016/j.mineng.2010.01.009

J. Gong and G. Zangari, "Electrodeposition of sacrificial tin–manganese alloy coatings," Materials Science and Engineering: A, vol. 344, no. 1, pp. 268-278, 2003/03/15/ 2003. https://doi.org/10.1016/S0921-5093(02)00412-4 DOI: https://doi.org/10.1016/S0921-5093(02)00412-4

Griskonis, E., Sulcius, and Zmuidzinaviciene, "Influence of temperature on the properties of Mn coatings electrodeposited from the electrolyte containing Te(VI) additive," Journal of Applied Electrochemistry, vol. 44(10), p. 1125, 2014. 10.1007/s10800-014-0733-8 DOI: https://doi.org/10.1007/s10800-014-0733-8

J. Rojas-Montes, R. Pérez-Garibay, and A. Uribe-Salas, "The Effects of an Anionic Membrane on the Electrodeposition of Manganese Ions: A Kinetic and Statistical Study. Journal of the Electrochemical Society, 161: D67-D72.," 2013. 10.1149/2.048401jes DOI: https://doi.org/10.1149/2.048401jes

Published

2022-04-07

How to Cite

Flores Santillán, C. G., Rojas Montes, J. C., Martínez Gómez, V. J., Martínez Casillas, D. C., Lucho Chigo, R., & Alcázar Medina, F. A. (2022). Evaluation of Alternative Additives to SeO2 in the Electrodeposition of Metallic Manganese. EPISTEMUS, 15(31), 49–55. https://doi.org/10.36790/epistemus.v15i31.198

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