PROPIEDADES VIBRACIONALES DE CARBUROS DE MOLIBDENO NANOESTRUCTURADOS
DOI:
https://doi.org/10.36790/epistemus.v10i20.19Keywords:
carburos nanoestructurados, metales de transición, nanomateriales, microscopía óptica, espectroscopía RamanAbstract
En este trabajo se hace un estudio de las propiedades vibracionales de espectroscopía micro Raman de carburos de molibdeno y sus correlaciones con los tamaños de fronteras de grano en función del tiempo de molienda, en atmosfera de gas de argón, y manteniendo la velocidad de molienda constante. La técnica de molienda mecánica de alta energía permitió mantener un control del tamaño de frontera de grano, la cual mostró, en leyes de potencia, dos regiones en función del tiempo de molienda. Mientras que por medio de espectroscopía micro Raman, se observaron cambios en los valores de las bandas principal (819.5 cm-1) y secundarias (894.0 y 778.7 cm-1). Las tres bandas estudiadas presentan un comportamiento línea en función del tiempo de molienda. Estos cambios que se presentan en las vibraciones Raman de estas bandas pudieron correlacionarse directamente con el tamaño de grano observado por microscopía óptica y por consecuencia del área superficial de las micropartículas de carburo de molibdeno. Las vibraciones en las bandas Raman, corresponden a cambios en las bandas...
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